Abstract

Commercially available aromatic diamines such as 4,4'-diamino diphenyl ether and 4,4'-diamino diphenyl methylene were treated with N-acetylsulf anilyl chloride to give the amino-sulf onamido-acetanilide derivatives. These derivatives were treated with 6 M hydrochloric acid to give the diamine monomers containing a preformed sulfonamide linkage. These monomers were polymerized with various diacid chlorides using a low temperature solution technique. Polymerizations using the Yamazaki reaction have also been investigated. The polymers obtained were characterized using infrared spectroscopy, thermal gravimetric analysis and differential scanning calorimetry.

Library of Congress Subject Headings

Sulfonamides; Polyamides; Organic compounds--Synthesis

Publication Date

5-1-1985

Document Type

Thesis

Department, Program, or Center

School of Chemistry and Materials Science (COS)

Advisor

Adduci, Jerry

Comments

Note: imported from RIT’s Digital Media Library running on DSpace to RIT Scholar Works. Physical copy available through RIT's The Wallace Library at: QP981.S82 R63 1985

Campus

RIT – Main Campus

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